首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   99749篇
  免费   5951篇
  国内免费   13016篇
化学   81488篇
晶体学   1276篇
力学   2347篇
综合类   878篇
数学   12868篇
物理学   19859篇
  2023年   768篇
  2022年   1305篇
  2021年   2061篇
  2020年   2679篇
  2019年   2489篇
  2018年   2155篇
  2017年   2965篇
  2016年   3242篇
  2015年   2697篇
  2014年   3695篇
  2013年   7442篇
  2012年   7109篇
  2011年   5445篇
  2010年   4670篇
  2009年   6361篇
  2008年   6566篇
  2007年   6908篇
  2006年   6262篇
  2005年   5357篇
  2004年   5026篇
  2003年   4220篇
  2002年   5273篇
  2001年   3177篇
  2000年   2988篇
  1999年   2794篇
  1998年   1978篇
  1997年   1683篇
  1996年   1438篇
  1995年   1625篇
  1994年   1364篇
  1993年   1144篇
  1992年   1068篇
  1991年   703篇
  1990年   587篇
  1989年   538篇
  1988年   402篇
  1987年   318篇
  1986年   294篇
  1985年   234篇
  1984年   253篇
  1983年   134篇
  1982年   218篇
  1981年   171篇
  1980年   196篇
  1979年   172篇
  1978年   147篇
  1977年   96篇
  1976年   75篇
  1974年   43篇
  1973年   45篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
The consequences of Ge deposition on Br-terminated Si(1 0 0) were studied with scanning tunneling microscopy at ambient temperature after annealing at 650 K. One monolayer of Br was sufficient to prevent the formation of Ge huts beyond the critical thickness of 3 ML. This is possible because Br acts as a surfactant whose presence lowered the diffusivity of Ge adatoms. Hindered mobility was manifest at low coverage through the formation of short Ge chains. Further deposition resulted in the extension and connection of the Ge chains and gave rise to the buildup of incomplete layers. The deposition of 7 ML of Ge resulted in a rough surface characterized by irregularly shaped clusters. A short 800 K anneal desorbed the Br and allowed Ge atoms to reorganize into the more energetically favorable “hut” structures produced by conventional Ge overlayer growth on Si(1 0 0).  相似文献   
102.
冻干溶液的低温显微研究与热分析   总被引:1,自引:0,他引:1  
利用低温显微系统研究了叔丁醇水溶液降温时的晶体形态,并利用差示扫描量热法(DSC)研究了溶液的反玻璃化结晶。低温显微实验表明:叔丁醇/水溶液结晶形状、大小与叔丁醇的浓度有关,浓度为10%时形成粗大的针状结晶, 有利于升华速率的提高。DSC实验表明:10%叔丁醇/10%蔗糖/水三元溶液的临界复温速率为250℃/min左右。  相似文献   
103.
蕴涵代数与BCK代数   总被引:6,自引:0,他引:6  
系统研究 Fuzzy蕴涵代数与 BCK代数之间的关系 ,给出 MV代数与 BCK代数之间的联系 ,建立正则 FI代数和对合 BCK代数的对偶代数  相似文献   
104.
Let T and S be invertible measure preserving transformations of a probability measure space (X, ℬ, μ). We prove that if the group generated by T and S is nilpotent, then exists in L 2-norm for any u, vL (X, ℬ, μ). We also show that for A∈ℬ with μ(A)>0 one has . By the way of contrast, we bring examples showing that if measure preserving transformations T, S generate a solvable group, then (i) the above limits do not have to exist; (ii) the double recurrence property fails, that is, for some A∈ℬ, μ(A)>0, one may have μ(AT -n AS - n A)=0 for all n∈ℕ. Finally, we show that when T and S generate a nilpotent group of class ≤c, in L 2(X) for all u, vL (X) if and only if T×S is ergodic on X×X and the group generated by T -1 S, T -2 S 2,..., T -c S c acts ergodically on X. Oblatum 19-V-2000 & 5-VII-2001?Published online: 12 October 2001  相似文献   
105.
This note shows that a certain toric quotient of the quintic Calabi-Yau threefold in provides a counterexample to a recent conjecture of Cox and Katz concerning nef cones of toric hypersurfaces. Received: 8 February 2001; in final form: 17 September 2001 / Published online: 1 February 2002  相似文献   
106.
Summary In 1980 Dahmen-DeVore-Scherer introduced a modulus of continuity which turns out to reflect invariance properties of compound cubature rules effectively. Accordingly, sharp error bounds are derived, the existence of relevant counterexamples being a consequence of a quantitative resonance principle, established previously.  相似文献   
107.
含铱配合物的聚对苯类电磷光聚合物   总被引:3,自引:3,他引:0       下载免费PDF全文
通过Suzuki聚合法合成了以聚对苯为主链的含铱配合物的电磷光共轭聚合物。部分苯环单元被β-二酮结尾的烷氧基链取代,进而与2-苯基吡啶配位形成悬垂的铱配合物侧链。宽带隙的聚对苯主链使主体与客体的能级匹配,从而有利于能量的转移。铱配合物通过长β-二酮结尾的烷氧基链悬挂在聚对苯的侧链上提高了聚合物的溶解性,有利于器件的制作。另外,由于连在氧原子上的β-二酮具有较大的旋转自由度,增大了β-二酮的反应活性有利于配位反应的进行。聚合物的EL光谱只显示客体铱配合物的发射,主体的发射已被完全猝灭。这表明聚合物主体和铱配合物客体之间发生了有效的能量转移。PPPIrPPy2聚合物发光器件的EL光谱发光波长为525nm,最大外量子效率为2.6%。  相似文献   
108.
在充分调研和分析SN方法粒子输运计算程序自动建模方法的基础上,对建模过程中的模型文件格式识别、属性编辑、空腔处理及自动划分离散网格等关键技术问题进行了研究,并提出了合理可行的解决方法。通过对SNAM程序建模部分功能测试,验证了这些方法的正确性和有效性。This paper presents two approaches to enhance the geometry modeling ability of SN particle transport simulation codes and focus on the key issues that lie in the processing from CAD model to SN code geometry model, e.g. CAD file format support, void modeling, mesh generation and model-editing. SNAM (SN Automatic Modeling system) has been developed as an interface code between commercial CAD software and SN particle transport simmulation codes. The testing results have shown that the algorithm and implementation used in SNAM are efficient and capable of all the necessary processing from CAD model to SN geometry model.  相似文献   
109.
孟庆格  李建国  周建坤 《中国物理》2006,15(7):1549-1557
Pr-based bulk metallic amorphous (BMA) rods (Pr60Ni30Al10) and Al-based amorphous ribbons (Al87Ni10Pr3) have been prepared by using copper mould casting and single roller melt-spun techniques, respectively. Thermal parameters deduced from differential scanning calorimeter (DSC) indicate that the glass-forming ability (GFA) of Pr60Ni30Al10 BMA rod is far higher than that of Al87Ni10Pr3 ribbon. A comparative study about the differences in structure between the two kinds of glass-forming alloys, superheated viscosity and crystallization are also made. Compared with the amorphous alloy Al87Ni10Pr3, the BMA alloy Pr60Ni30Al10 shows high thermal stability and large viscosity, small diffusivity at the same superheated temperatures. The results of x-Ray diffraction (XRD) and transmission electron microscope (TEM) show the pronounced difference in structure between the two amorphous alloys. Together with crystallization results, the main structure compositions of the amorphous samples are confirmed. It seems that the higher the GFA, the more topological type clusters in the Pr-Ni-Al amorphous alloys, the GFAs of the present glass-forming alloys are closely related to their structures.  相似文献   
110.
Electron spin resonance spectra of Mn2+ in diluted solid solutions of MnO2 in Y2O3 have been studied at room temperature for Mn concentrations between 0.20 and 2.00 mol%. Isolated Mn2+ ions in sites with two different symmetries were observed, as well as Mn2+ ions coupled by the exchange interaction. The relative concentration of isolated to coupled Mn2+ ions decreases with increasing manganese concentration. The results are consistent with the assumption that the manganese ions occupy preferentially the C2 symmetry sites. A theoretical calculation based on this model yields an effective range of the exchange interaction between Mn2+ ions of 0.53 nm, of the same order as that of Mn2+ ions in CaO.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号